Analysis of Morpholine in Water by UV Visible Spectrophotometer
Keywords:
Morpholine ,Alkalinity, Corrosion, Spectrophotometer etc.Abstract
Feedwater is the aggregate of the total condensate return and the boiler makes up water. The reasons to control pH are low pH or insufficient alkalinity can result in a corrosive acidic attack, dissolved oxygen can cause pitting loss of protective oxide film 4Fe3O4 + O2?6Fe2O3 & high pH or excess alkalinity can result in caustic gouging/cracking and foaming, with resultant carryover Fe3O4 + 4NaOH = 2NaFeO2 + Na2FeO2 + H2O, The corrosion rate of carbon steel at feedwater temperatures approaches pH > 8.5. To maintain the pH of feed water (>8.5) small amounts of Morpholine are dosed. It is completely miscible in water and stable in hot liquid and gaseous phases at all temp. Morpholine has the ability to maintain corrosion protection by neutralizing acid constituents such as carbonic acid, throughout the entire boiler system.
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********
2. Hg.Seiler,A.Sigel, H.Sigel; HandBook of ëToxicity of Inorganic Compoundsí, Marcel Dekker New York, (1998).
3. E.Pichard, G.M.Mackay,J.Points; ëTraceAnalysis; AStructureApproach toObtainingReliableResultsí, The Royal Society of Chemistry, U.K., 38 (1996).
4.R.Renner; Envorn.Sci.Technol., 29, 256 (1995).
5. A.D.Kakal, F.E.Hahn, K.N.Raymond;J.Am.Chem. Soc., 112, 1519 (1990).
6. Bowen, H.J.M., J. Nucl. Energy. 3, 18, 1956.
7. Lassiter, J.W. and Morton, J.D., J. Anim, Sci., 27, 776, 1968.
8.. Dewar, W.A., Teague, P.W. and Downie, J.N., Br. Poult. Sci., 15, 119, 1974.
9. Yin, Zhaobao; Jiang, Haiyan; Lee, Eun-Sook Y.; Ni, Mingwei; Erikson, Keith M.; Milatovic, Dejan; Bowman, Aaron B.; Aschner,
Michael Journal of Neurochemistry 112 (5); 2010.
10. Underwood, E.J. Trace elements in Human and Animal Nutrition, Academic press: New York; P 170, 1977.
11. Critchfield, J.W; Carl, E.F, Keen, C.L.Epil.Res. 15, 3, 1993.
12. Kazi, T.G; Afridi, H. I, Kazi, N: Jamali, M.K.; Arain, M.B,; Jalbani, N.; Kandhro, G.A. Biol Trace Elem Res 122,1, 2008.
13. Cotzias, G.C., Physiol Rev., 38, 503, 1958.
14. Donaldson, J. in Manganese Neurotoxicity in Metal Ions in Neurology & psychiatry, Gobay, S,; Harris, J.; Ho, B.T (Eds.), Alan R.
Liss: New York; 259, 1985.
15. Leach, R.M. in Trace Elements in Human Health and Disease, Vol; 2, Prasad, A.S.; Oberleas, D. (Eds.), Academic Press: New York:P235. 1976:
16. Soko, L.; Chimuka, L.; Cukrowska, E.; Pole, S.Anal.Chim. Acta 485, 25. 2003.
17. Cersosimo, M.G.; Koller, W.C. "The diagnosis of manganese- induced parkinsonism. NeuroToxicology 27: 340346 2007.
18. Purris E.R and Peterson, N.K., Soil Sci., 81, 223, 1956.
19. Gorsuch, T.T. Analyst, 84, 135, 1959.
20. Bulut, V. N.; Gundogdu, A.; Duran, C.; Senturk, H. B.; Soylak, M.; Elci, L.; Tufekci, M. J. Hazard. Mater. 2007, 146, 155-163.
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22. Pancras, J. P.; Puri, B. K. Anal. Bioanal. Chem. 2002, 374, 1306-1311.
23. Ramesh, A.; Mohan, K. R.; Seshaiah, K. Talanta 2002, 57, 243-252.
24. Yang, G.; Dong, X.; Hu, Q.; Yin, J. Anal. Lett. 2002, 35, 1735-1745.
25. Sharma, R. K.; Puri, A.; Kumar, A.; Monga, Y.; Gaba, G.; Adholeya, A. Sep. Sci. Technol. 2014, 49, 709-720.
26. Rezaei, B.; Sadeghi, E.; Meghdadi, S. J. Hazard. Mater. 2009, 168, 787-792.
27. Chandra Rao, G. P.; Veni, S. S.; Pratap, K.; Koteswara Rao, Y.; Seshaiah, K. Anal. Lett. 2006, 39, 1009-1021.
28. Kanchi, S.; Singh, P.; Bisetty, K. Arabian J. Chem. 2014, 7, 11-25.
29. Tuzen, M.; Saygi, K. O.; Soylak, M. J. Hazard. Mater. 2008, 152, 632-639.
30. Arain, M. A.; Wattoo, F. H.; Wattoo, M. H. S.; Ghanghro, A. B.; Tirmizi, S. A.; Iqbal, J.; Arain, S. A. Arabian J. Chem. 2009, 2, 25-29.
31. Afkhami, A.; Madrakian, T.; Bozorgzadeh, E., Bahram, M. Talanta 2007, 71, 1103-1109.
32. Arvand, M.; Abolghasemi, S.; Zanjanchi, M. A. J. Anal. Chem. 2007, 62, 342-347.
33. Karayunlu, S.; Ay, U. J. Anal. Chem. 2010, 65, 244-48.
34. Ghaedi, M. Spectrochim. Acta A 2007, 66, 295-301.
35. Shar, G. A.; Bhanger, M. I. J. Chem. Soc. Pak. 2002, 24, 185-189.
36. Zaijun, L.; Yuling, Y.; Jian, T.; Jiaomai, P. Talanta 2003, 60, 123-130.
37. Topuz, B.; Macit, M. Environ. Monit. Assess. 2011, 173, 709-722.
38. Hejazi, L.; Mohammadi, D. E.; Yamini, Y.; Brereton, R. G. Talanta 2004, 62, 185-191.
39. Golcu, A. Transit. Met. Chem. 2006, 31, 405-412.
40. Sharma, S.; Rahman, N.; Azmi, S. N. H.; Iqbal, B.; Amburk, M. I. B. B.; Al Barwani, Z. M. H. J. Chin. Chem. Soc. 2010, 57, 622-631.
41. Reddy, K. J.; Kumar, J. R.; Narayana, S. L.; Ramachandraiah, C.; Thriveni, T.; Reddy, A. V. Environ. Monit. Assess. 2007, 124, 309-320.
42. Sarma, L. S.; Kumar, J. R.; Reddy, K. J.; Reddy, A. V. J. Agr. Food. Chem. 2005, 53, 5492-5498.
43. Topuz, B.; Macit M. In: 6th Aegean Analytical Chemistry Days; Pamukkale University: Denizli, Turkey, 2008.
44. Topuz, B.; Okur, G. In: 1st International Black Sea Congress on Environmental Sciences ; Giresun, Turkey, 2016
45. Agrawal A, Kumar P, Dwivedi D. K., Baghel H.K, Analysis of Methanol in Water Sample by Gas Chromatography International Journal of Multidisciplinary Research Education Analysis and Development-IJMREAD,2021,1(2),72-81.
********
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2021-12-25
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Agrawal, D. A., Dwivedi, D. K., & Srivastava, D. R. (2021). Analysis of Morpholine in Water by UV Visible Spectrophotometer. International Journal of Multidisciplinary Research Education Analysis and Development- IJMREAD, 81–89. Retrieved from https://ijmread.com/index.php/ijmread/article/view/50
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Copyright (c) 2021 Dr. Atul Agrawal, Dr. Pramod Kumar, Dharmendra Kumar Dwivedi
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